![]() DCM can eventually lead to congestive heart failure.ĭCM is a very serious condition that requires intensive treatment and not all dogs will return to normal. The symptoms of the disease may occur suddenly or progress gradually as the disease worsens over time. Dilated Cardiomyopathy (DCM)ĭilated cardiomyopathy (DCM) is degeneration of the heart that causes the muscle of the left ventricle to become very thin and pump weakly. It is important to recognize that treatment is generally only recommended by veterinary oncologists for as long as quality of life can be maintained. Chemotherapy, immunotherapy, and/or radiation therapy may be recommended. Referral for consultation with a boarded veterinary oncologist is recommended. Surgery is often used to remove the affected tissue. Talk with your vet to learn the risks and benefits of early spaying for your dog.ĭepending on the type of cancer that a Boxer develops, treatments may vary. Spaying prior to the first heat cycle substantially decreases the risk of developing mammary cancer in adulthood. Mast cell tumors (which can be on the skin or internal organs)Ĭanine lymphoma (a cancer of the lymph nodes and lymph system) CancersĬancers are some of the most common health conditions seen in Boxers. Boxer Dog Health Issuesīoxers are predisposed to a few health conditions including cancer, heart disease, and joint problems. Their high energy and spirited nature typically make Boxers good pets for the active household.īoxers are prone to health issues, so it is important to talk with your veterinarian and have a strong preventative health routine in place. They have a prominent lower jaw and a short nose, which makes them sensitive to overheating. In the past, many Boxers had their ears cropped, but this trend has grown less popular in recent years. They are considered a medium-sized dog breed-weighing in around 65-80 pounds with an average height of 21-23 inches. The Boxer dog breed is deep-chested and is usually well-muscled under its smooth coat. Interestingly, in 2005, a Boxer’s DNA was used to sequence the canine genome. The Boxer is used today by the police and military. This history means they are excellent runners and playful jumpers. They were used for bull-baiting and to chase wild game. ![]() The Boxer as it is known today was imported to the United States from Germany in the 1930s.
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Unless we have indicated our desire to share your nonpublic personal information with non-affiliated third parties (by checking the box in the section below), we share information:Ī) For everyday business purposes, such as to process transactions, maintain account(s), respond to court orders and legal investigations, or report to credit bureaus.ī) For purposes of processing a sale or lease transaction as your request or authorize, such as submitting information to third party financial institutions that may be requested to take an assignment of the contract or verifying insurance coverage information.Ĭ) When using outside service providers to help us provide you with products and services. We prohibit our employees and agents from giving information about you to anyone in a manner that would violate any applicable law or our privacy policy. We restrict access to nonpublic personal information about you to those employees and outside contractors who need to know the information to provide product or service to you. We maintain physical and electronic safeguards that comply with state and federal law. We safeguard nonpublic personal information according to established industry standards and procedures. Examples would be a driver's license or social security number. This information may be required even if you were to pay cash for your vehicle. Some of the information we obtain from you may be required by state of federal agencies, such as the Department of Motor Vehicles or the Internal Revenue Service. We may also obtain information from third parties such as employers, references and insurance companies. We may also obtain information from a credit-reporting agency. For example, if we sell or lease you a vehicle - extending you credit at your request - we will receive information from you in order to determine your creditworthiness. The purchase of a motor vehicle requires considerable accumulation of nonpublic personal information. Please take a moment to read this entire policy. This document explains our privacy policy, gives you reasons why we ask for the type of information we do, and if we do reserve a right to share information with non-affiliated third parties, lets you "opt-out" of our reservation to do so. ![]() ![]() As a valued customer, we want to ensure your private information is kept private and only shared with those companies who are authorized either by yourself or as allowed or required by law. ![]() ![]() It then flew out of the Hall of Armors and went towards the Roxxon Oil Rig together with the other 35 armors. along with all the other armors in the basement of Tony's Malibu Mansion, under the House Party Protocol ordered by Tony. The Mark XXXIII was activated by J.A.R.V.I.S. Iron Man 3 Activation of the "House Party Protocol" With unique features and abilities, the Mark XXXIV / Southpaw was created. With Silver Centurion's completion, Stark proceeded to work on a new type of suit for Disaster Rescue missions. It was presumed that the armor was tested a number of times before it was fully functional and ready for combat.Īfter completing the armor, Stark stored it in the Hall of Armors Chamber beneath his Malibu House, where all the other previous Iron Man Armors he completed were stored in as well. After the Mark XXXII / Romeo's completion, Stark proceeded to working on his next armor, the Mark XXXIII. Sometime after the Battle of New York, Tony Stark, who was haunted by his near death experience from the event, suffered from post traumatic stress disorder, became paranoid and obsessed with security.īecause of this, Stark began working on the Iron Legion, and through its development, created several Iron Man Armors, from the Mark VIII to the Mark XXXII all featuring various designs and purposes. History Before Iron Man 3 The Iron Legion and Creation This armor contained numerous infrared flares, another feature common with some of its predecessors. The armor also features extendable Vibranium Blades that can be quickly activated from the armor's gauntlets. It's Unibeam is in a shape of a trapezoid-like triangle shaped piece, and is surrounded by another batch of triangular plates that make up the whole part of the armor's chest piece. The Mark XXXIII features a triangular Unibeam in it's chest piece, which uses the new and improved New Element Arc Reactor Mark II. The Mark XXXIII is equipped with more powerful repulsors, but uses the standard Repulsor technology. It can flexibly open itself to allow Tony to enter into the suit and automatically wrap itself around him, anywhere at anytime, much like the Mark XLII's technology and the other newly built Mark suits'. The Mark XXXIII, along with all the other newly built Mark suits, uses a more advanced technology that was based off on the Mark VII's technology, which is able to wrap itself around Tony's body, without the aid of robotic arms or any external mechanics. ![]() The Mark XXXIII has powerful repulsor propelled thrusters equipped on its back. The armor features an extendable Blade that can be quickly activated from both of the armor's gauntlets. The Mark XXXIII has an Enhanced Energy Output that allows it to transfer energy to the various Repulsors in it's system, including the Unibeam. It's armor plating are not boxy and square like like it's predecessors but more sleek and triangular, giving it a sharp, crisp look.Īrmor Capabilities Enhanced Energy Output It was designed for energy amplification and redirection, and thus has a distinctive body shape, being angular and polygonal. The Mark XXXIII suit is primarily deep crimson red in color, with golden and silver highlights, and features a triangular shaped Unibeam together with it's chest piece, which follows the shape of the Unibeam. REDESIGNED ENHANCED ENERGY SUIT WITH UPGRADED CHEST RT FOR HIGH-ENERGY OUTPUT AND OUTFITTED WITH RETRACTABLE GAUNTLET BLADE. 6.2 Marvel's Iron Man 3 - JARVIS: A Second Screen Experience.5.2.1 Activation of the "House Party Protocol". However, the lawyer said she believes Brown has violated ethics codes in requiring support for his priorities in exchange for supporting other efforts. Elissa Slotkin for projects.Īn attorney hired to investigate said in a report that she could not substantiate the first or second allegation. Going beyond his official capacity in seeking congressional funding through Rep.Offering support for a Lansing Housing Commission resolutions in exchange for the LHC paying an individual's tenant late fees out of a "slush fund".Offering support for a development project in return for the developer making an individual's rent payments.LANSING - The full City Council Monday is set to accept an ethics complaint report made by a group of City Council members and Lansing Mayor Andy Schor against first-term Council member Jeffrey Brown that could result in a range of disciplinary actions, up to expulsion from the Council.īrown, who was the second-highest vote-getter in the November 2021 city election for an at-large seat, was accused by Schor and the council majority in March of three violations: Her gender was incorrect in an earlier version of this story. Correction: Gouri Sashital is a partner with the Southfield-based law firm Keller Thoma. ![]() But like your wonky television, your car may only react to this fix temporarily-just long enough to get you to your nearest service center. Know how you can sometimes bang on the side of an old TV to bring the picture back into focus? It's kind of like that. In some cases, this gentle tapping can help power it back up, since you’ll be tapping the electrical components back in contact with each other. Try lightly tapping the starter a few times with a hard object, making sure not to pound it. A weak or dead battery, or even faulty battery cables, could be causing the problems with your car, not the starter. ![]() ![]() Look under the hood.Ĭheck the battery and battery cables to see whether everything’s in working order. How do you troubleshoot starter problems?Īssuming you’ve already tried to start and jumpstart your car, try one of the following troubleshooting tips. Damaged or worn-out parts in the starter system.Dirty or corroded connections at the starter.What causes starter problems?Ī variety of problems can lead to a bad starter, including: Unfortunately, what starts out as a few drops of oil can slowly and sometimes unnoticeably turn into an expensive problem, so keep an eye out for oil leaks to avoid starter issues of this nature. If you pop the hood only to find that your starter is drenched in engine oil, your bad starter might be a symptom of another problem-an oil leak. They can also be located just under the intake manifold on some vehicles. Or if it is FWD, check on the drivers side above the transmission or under the exhaust manifold. Your starter can usually be found on the passenger's side (if RWD) of the engine, just below the exhaust manifold. If you see or smell smoke, call for help rather than turning the key harder, again! 5. When you’ve been desperately attempting to start your car, the starter can overheat making electrical issues-and the accompanying smoke-more likely. The starter is part of your car’s electrical system and subject to blown fuses and short circuits. If a jumpstart won’t fire up your engine, nothing other than a certified technician will! 4. Is your engine not revving up, even after attempting a jumpstart? At this point, it’s time to call roadside assistance and get your car to the nearest Firestone Complete Auto Care. If you try to start the engine only to find that the dashboard lights up, but the engine doesn’t power up, you might have a problem with the starter. However, a starter can die without making any sound at all, or it may announce its impending death with whirring and grinding noise-so listen up! 2. One of the symptoms of a bad starter is a clicking noise when you turn the key or push the start button. Without a properly working starter relay and motor, you won’t be able to start your vehicle and may need a tow. A starter relay sits between the battery and the starter motor, transmitting power. The starter is a small motor, powered by the battery. Read up on bad starter symptoms and learn how to tell them apart from other problems. Are you wondering why your car won’t start? Issues with the starter system are more common than you think, but drivers often confuse them with other car troubles. ![]() The majority of the fake pairs the LegitGrails team has spotted had a rather curved toe box please refer to the Jordan 1 TS Fragment real vs fake comparison below. The toe box is another great detail to be verified. Our legit check team has noticed a great tendency in the replica Fragment x Travis Scott Jordan 1: the fakes tend to have a yellow-ish midsole, while the authentic pairs have a much purer shade of white. ![]() There must be three levels of the grains on the midsole that are visibly separated. The counterfeits tend to miss out on the correct grain pattern. The rubber midsole is often a great reference point for a Jordan 1 Fragment legit check. Moving along the outer side of the shoe, pay attention to the toe box of your pair. How to Authenticate Jordan 1 High Fragment TS: The Toe Box In the lower grade replicas, the gap between the Swoosh and the stitching is often very big. In the real vs fake Travis Scott Fragment Jordan 1 comparison, notice the placement of the Swoosh’s tip relative to the corner stitching. Remember to also check the position of the reverse Swoosh - the signature Jordan 1 Cactus Jack feature. The fake Fragment x Travis Scott Air Jordan 1 High would often have sloppy cuts, making the strips appear messy. Talking about the leather details, make sure you examine the leather strips around the eyelets. The heel of an authentic Jordan pair should be rather straight, while still having some difference between the levels of leather. ![]() Look at the heel area from the side: the replica Jordan 1 TS Fragments often appear more bent, compared to a real pair. Jordan 1 Fragment x Travis Scott Legit Check: The Overall ShapeĪt the very beginning, you should inspect the overall look of your pair. ![]() Here are the steps to delete the .plist file from the /Library/LaunchAgents folder: This will prevent Microsoft AutoUpdate from running automatically, but you can still launch the app manually to check for updates. If you want to keep the ability to manually check for updates, you can delete only the .plist file from just the /Library/LaunchAgents folder, and leave the other two files in place. This means that you won’t be able to check for updates manually using the Microsoft AutoUpdate app, and you’ll need to download and install updates manually from Microsoft’s website. However … If you delete all three of them, it will completely prevent Microsoft AutoUpdate from running on your Mac, whether it’s automatically or manually. Some articles and forums suggest deleting all three of them. The .plist file is the main launch agent for Microsoft AutoUpdate, and it is located in three places as detailed here: Let’s call it Method 2.5 … How to disable Microsoft AutoUpdate (Method 2.5) In which case, here’s another approach that might work. So if you use Edge you may find that you’re having to reapply the changes more often than you’d like. It seems to me that Edge has a far more aggressive update routine, and it over-writes the setting changes I’ve suggested below on a regular basis. Since first publishing this “Method 2” article I’ve installed the Microsoft Edge browser (as I wanted to test out Microsoft’s ChatGPT integration on the search engine, and it’s only available when using Edge). (Update) - Another Updated / Alternative Method It can be run manually, so there’s no reason for force it upon the user to have it running automatically. Microsoft provides no way to disable MAU from running every day. So aside from the potential annoyance factor from the daily pop-ups, it may slow down the computer. Some users report excessive CPU usage from MAU. This seems to only prevent it automatically downloading and installing updates, but does not stop MAU from running every day. It runs and pops-up even if “ Automatic Updates: Automatically download and install” is disabled. I’ve read that for some people this occurs even if there are no updates available. After your changes have been saved, you can simply replace the original file with your copy (macOS will ask you to enter your admin password).If you have installed Microsoft applications (such as Office) on your Mac computer, you’ve likely noticed Microsoft AutoUpdate (MAU) pops up every day to tell you if there are updates available. You might also want to first make a copy of the plist file into a non-restricted folder (your desktop for example) otherwise VSCode will throw you an error on save due to restrictions on the original LaunchAgent folder. How to edit the plist file: I use VSCode with the extension called Binary Plist to decode the plist to xml then encode it back to binary on save. If you choose to do that you need to leave the agent enabled: Disabled You can if you want also make the AutoUpdate run at the interval of your choice by setting the desired number of seconds under: StartInterval Library/Application Support/Microsoft/MAU2.0/Microsoft AutoUpdate.app/Contents/MacOS/Microsoft Update Assistant.app/Contents/MacOS/Microsoft Update Assistant Go to: /Library/LaunchAgents/ then look for a file called .plistĮdit (more info at the bottom on how to edit a plist file) the file and replace the text with: "rolled gold plate" provided the proportional fraction and fineness designations are also shown. No article having a gold alloy portion of less than one-twentieth by weight may be marked "gold-filled," but articles may be marked Lower limits are permitted in some countries. Having a gold alloy coating of less than 10-karat fineness may have any quality mark affixed. A quality mark may be used to show the quantity and fineness of the gold alloy. The term "gold-filled" is used to describe articles of jewelry made of base metal which are covered on one or more surfaces with a The jewelry industry, the common unit of measure is the pennyweight (dwt.) which is equivalent to 1.555 grams. One troy ounce is equivalent to 20 troy pennyweights. The basic unit of weight used in dealing with gold is the troy ounce. "Karat" should not be confused with "carat," a unit of weight used for precious stones. ![]() Incidentally, 14K gold is commonly used in jewelry manufacture. Thus, 14-karat (14K) gold indicates a composition of 14 parts of gold and 10 parts of other metals. "Karat" indicates the proportion of solid gold in an alloy based on a total of 24 parts. For example, a gold nugget containing 885 parts of pure gold and 115 parts of other metals, such as silver and copper, would be considered 885-fine. "Fineness" defines gold content in parts per thousand. The degree of purity of native gold, bullion (bars or ingots of unrefined gold), and refined gold is stated in terms of gold content. The material is then processed to remove the gold. ![]() The firehose blasts the sediment outcrop, washing away sand, clay, gravel and gold particles. Hydraulic placer mining at Lost Chicken Hill Mine, near Chicken, Alaska. The difference in density enables gold to be concentrated by gravity and permits the separation of goldįrom clay, silt, sand, and gravel by various agitating and collecting devices such as the gold pan, rocker, and sluicebox. Impure gold, as it commonly occurs in deposits, has a density of 16 to 18, whereas the associated waste rock (gangue) has aĭensity of about 2.5. The specific gravity or density of pure gold is 19.3 compared to 14.0 for mercury and 11.4 for lead. It is the most malleable and ductile of metals. Pure gold is relatively soft-it has about the hardness of a penny. Silver, copper, nickel, platinum, palladium, tellurium, and iron, with gold create various color hues ranging from silver-white to green and orange-red. Its chemical symbol Au isĭerived from the Latin word "aurum." In pure form gold has a metallic luster and is sun yellow, but mixtures of other metals, such as Gold is called a "noble" metal (an alchemistic term) because it does not oxidize under ordinary conditions. Prospectors worked stream sediments to find tiny nuggets that they would sell or trade for supplies. Gold nuggets: Small nuggets of gold obtained by panning. New World, and many gold and silver objects were melted and cast into coins and bars, destroying the priceless artifacts of the Indian culture. The Conquistadores plundered the treasuries of these civilizations during their explorations of the The gold in the Aztec and Inca treasuries of Mexico and Peru believed to have come from Colombia, although some undoubtedly was Recovered from this region during the reign of King Solomon (961-922 B.C.). Recent studies of the Mahd adhĭhahab (meaning "Cradle of Gold") mine in the present Kingdom of Saudi Arabia reveal that gold, silver, and copper were When these mines could no longer meet their demands, deposits elsewhere, possibly in Yemen and southern Africa, were exploited.Īrtisans in Mesopotamia and Palestine probably obtained their supplies from Egypt and Arabia. ![]() The region of the Upper Nile near the Red Sea and in the Nubian Desert area supplied much of the gold used by the Egyptian The ancient civilizations appear to have obtained their supplies of gold from various deposits in the Middle East. These elegant works of art were created by skilled craftsmen more than 3,500 years ago. Yielded a great variety of gold figurines, masks, cups, diadems, and jewelry, plus hundreds of decorated beads and buttons. The graves of nobles at the ancient Citadel of Mycenae near Nauplion, Greece, discovered by Heinrich Schliemann in 1876, Some of these items, called "Treasures of Tutankhamun," attracted more than 6 million visitors in six cities during a This young pharaoh ruled Egypt in the 14th century B.C. Particularly noteworthy are the gold items discovered by Howard Carter and LordĬarnarvon in 1922 in the tomb of Tutankhamun. Of ancient civilizations used gold lavishly in decorating tombs and temples, and gold objects made more than 5,000 years ago have been found in Egypt. Other elements, because it is beautiful and imperishable, and because exquisite objects can be made from it. Gold was among the first metals to be mined because it commonly occurs in its native form, that is, not combined with So we’re re-thinking it all with ingenuity, science and grit. And no one likes receiving a crunched package. What to do with a well-loved or defective product is blurry. Customized goods and next-day delivery are norms. The last phase of a product’s life-getting it to athletes* and, eventually, back from them-is the most challenging sustainability puzzle. ![]() We aren’t there yet, but just like our athletes constantly working to be better than they were before, progress is an every day goal. At scale, these adjustments and innovations are our path to achieving our aims of 100% of the waste from our extended supply chain diverted from landfills and at least 80% recycled back into NIKE products and other goods. Since our last Impact Report, we’ve made single digit centimeter adjustments across product manufacturing meaning more than 3.5 million kg of waste was prevented. Small changes pave the way to achieve big aims. This ensures all Nike Air soles are made with at least 50% recycled material. We’re able to reuse more than 90% of the waste from Air manufacturing, often turning it into new Air bags. It’s also one of our most sustainable innovations. One of our greatest inventions is Nike Air. But there is a growing truth of waste: trash is treasure. And today, that process also makes waste. Our end-to-end approach looks at carbon, energy, waste, chemistry and water across the entire product lifecycle, ultimately making choices that improve conditions for teams and locations worldwide.Ĭreating products takes energy. ![]() ![]() Sustainable materials matter that much more if our manufacturing is done responsibly. Rutherford’s earlier model of the atom had also assumed that electrons moved in circular orbits around the nucleus and that the atom was held together by the electrostatic attraction between the positively charged nucleus and the negatively charged electron. Bohr’s model required only one assumption: The electron moves around the nucleus in circular orbits that can have only certain allowed radii. In 1913, a Danish physicist, Niels Bohr (1885–1962 Nobel Prize in Physics, 1922), proposed a theoretical model for the hydrogen atom that explained its emission spectrum. This spectrum contains dark lines on bright. Where \(n_1\) and \(n_2\) are positive integers, \(n_2 > n_1\), and \( \Re \) the Rydberg constant, has a value of 1.09737 × 10 7 m −1. Absorption spectrum : The spectrum produced by absorbed radiation is known as absorption spectrum. Emission and absorption of light Emission line spectrum Continuous spectrum (thermal, blackbody) Independent of composition Dependent on composition Each element has its own unique spectrum Absorption lines in the Sun’s spectrum Gustav Kirchhoff (1824-1887) The Balmer series for hydrogen: Visible light electrons falling to n2 Rydberg formula. Complete details will be published later.\] The 4 lines of the visible hydrogen spectrum (the Balmer series) correspond to wavelengths of 410.2, 434.0, 486.1 and 656.3 nanometres (nm). The long wave-length limit of the continuous absorption compares well with the theoretical value 14.4 volts. If you put a high voltage across this (say, 5000 volts), the tube lights up with a bright pink glow. Often the absorption spectrum consists of a set of. Dioxane, Ethyl Acetate & 3 Few Tertiary Amines. Stellar spectra are approximately a black body spectrum, but this mostly holds true for the most hot and luminous O and B type stars for cooler stars, the image already gets quite a bit more muddled, as they will show more and more absorption happening in the stellar photosphere, as well as other effects that ruin the nice, smooth black body sp. A hydrogen discharge tube is a slim tube containing hydrogen gas at low pressure with an electrode at each end. These states give rise to hydrogen-like series of absorption lines in the optical absorption spectrum of Cu 2 O at the photon energies described by the Rydberg formula, E n E gap Ry X /n 2. The pattern of absorbed wavelengths is known as the absorption spectrum of the atoms or molecules. Electronic Absorption Spectra & Hydrogen Bonding: Phenols with. ![]() This continuous absorption corresponds to the dissociation of the molecule into a normal and an excited atom. What is an emission spectrum Observing hydrogens emission spectrum. ANALYSIS OF THE PURE ROTATIONAL ABSORPTION SPECTRA OF HYDROGEN SULFIDE AND DEUTERIUM SULFIDE. A continuous absorption spectrum begins sharply at 840. ![]() This adds a new electronic level to the three already obtained (Dieke and Hopfield, Oakland Meeting of the American Physical Society, June 1926) from the hydrogen emission spectrum. In absorption spectrum of hydrogen atom, only one electron is present in its one atom which is in ground state, so it means that all electrons can only absorb energy of photon of wavelength which lies in UV region to get to a higher energy state (by calculation it can take max wavelength 122.55nm and minimum wavelength 91.9nm).Then why do we s. At least twelve bands of this progression were easily recognised. The most striking feature of the spectrum is a progression of strong absorption bands beginning with 1105. Most of the bands were clearly resolved and show the characteristic structure of the emission bands in the ultra-violet. The samples emission spectrum will be missing from the. More than twenty absorption bands were observed between λλ1245 and 840. An Absorption Spectrum is produced by shining white light through a sample of a gaseous element. Hydrogen spectrum (absorption or emission) is an impotent type of tool for the determination of the atomic structure of chemical elements or atoms in. WITH the continuous spectrum described by Lyman ( Astrophysical Jour., 60, 1) as a background, and with hydrogen flowing through the receiver of the spectrograph, it was found possible to photograph the absorption spectrum of molecular hydrogen in the extreme ultra-violet. |
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